Comprehensive Solubility Rules Table Dataset

Key Takeaways

  • Access 31 key solubility rules for various ions and compounds.
  • Explore detailed exceptions and notes for each solubility guideline.
  • Download a ready-to-use reference for chemistry coursework and lab work.
  • Get practical examples of soluble and insoluble compounds.
Showing 31 of 31
Ion/Compound Type Formula Solubility Exceptions/Notes Category Examples
NitratesNO₃⁻SolubleNone - all nitrates are solubleAlways SolubleNaNO₃, KNO₃, AgNO₃, Pb(NO₃)₂
AcetatesCH₃COO⁻ (C₂H₃O₂⁻)SolubleSilver acetate is slightly solubleAlways SolubleNaCH₃COO, KC₂H₃O₂, Ca(CH₃COO)₂
ChloratesClO₃⁻SolubleNone - all chlorates are solubleAlways SolubleNaClO₃, KClO₃, Ba(ClO₃)₂
PerchloratesClO₄⁻SolubleKClO₄, RbClO₄, CsClO₄ are slightly solubleAlways SolubleNaClO₄, Mg(ClO₄)₂, Ca(ClO₄)₂
Alkali Metal IonsLi⁺, Na⁺, K⁺, Rb⁺, Cs⁺SolubleNone - all Group 1 salts are solubleAlways SolubleNaCl, KBr, Li₂SO₄, CsNO₃
AmmoniumNH₄⁺SolubleNone - all ammonium salts are solubleAlways SolubleNH₄Cl, NH₄NO₃, (NH₄)₂SO₄, NH₄OH
Halides (Cl⁻, Br⁻, I⁻)Cl⁻, Br⁻, I⁻Mostly SolubleAg⁺, Pb²⁺, Hg₂²⁺ halides are insolubleSoluble with ExceptionsNaCl, KBr soluble; AgCl, PbI₂ insoluble
FluoridesF⁻Mostly SolubleGroup 2 fluorides (MgF₂, CaF₂, BaF₂) and PbF₂ are insolubleSoluble with ExceptionsNaF, KF soluble; CaF₂, BaF₂ insoluble
SulfatesSO₄²⁻Mostly SolubleBaSO₄, PbSO₄, HgSO₄, CaSO₄, SrSO₄, Ag₂SO₄ are insoluble or slightly solubleSoluble with ExceptionsNa₂SO₄, MgSO₄ soluble; BaSO₄, PbSO₄ insoluble
CarbonatesCO₃²⁻Mostly InsolubleAlkali metal and ammonium carbonates are solubleInsoluble with ExceptionsCaCO₃, BaCO₃ insoluble; Na₂CO₃, K₂CO₃ soluble
PhosphatesPO₄³⁻Mostly InsolubleAlkali metal and ammonium phosphates are solubleInsoluble with ExceptionsCa₃(PO₄)₂, Ag₃PO₄ insoluble; Na₃PO₄ soluble
ChromatesCrO₄²⁻Mostly InsolubleAlkali metal and ammonium chromates are soluble; MgCrO₄, CaCrO₄ are solubleInsoluble with ExceptionsPbCrO₄, BaCrO₄, Ag₂CrO₄ insoluble; K₂CrO₄ soluble
SulfidesS²⁻Mostly InsolubleAlkali metal, alkaline earth, and ammonium sulfides are solubleInsoluble with ExceptionsCuS, PbS, Ag₂S insoluble; Na₂S, (NH₄)₂S soluble
HydroxidesOH⁻Mostly InsolubleAlkali metal hydroxides are soluble; Ca(OH)₂, Sr(OH)₂, Ba(OH)₂ are slightly solubleInsoluble with ExceptionsFe(OH)₃, Al(OH)₃ insoluble; NaOH, KOH soluble
OxidesO²⁻Mostly InsolubleAlkali metal oxides react with water to form soluble hydroxides; CaO, SrO, BaO slightly solubleInsoluble with ExceptionsFe₂O₃, Al₂O₃ insoluble; Na₂O reacts with water
SulfitesSO₃²⁻Mostly InsolubleAlkali metal and ammonium sulfites are solubleInsoluble with ExceptionsCaSO₃, BaSO₃ insoluble; Na₂SO₃ soluble
OxalatesC₂O₄²⁻Mostly InsolubleAlkali metal and ammonium oxalates are solubleInsoluble with ExceptionsCaC₂O₄, BaC₂O₄ insoluble; Na₂C₂O₄ soluble
Silver ChlorideAgClInsolubleDissolves in NH₃ solution forming [Ag(NH₃)₂]⁺Common PrecipitateWhite precipitate, Ksp = 1.8 × 10⁻¹⁰
Silver BromideAgBrInsolubleLess soluble than AgClCommon PrecipitateLight yellow precipitate, Ksp = 5.0 × 10⁻¹³
Silver IodideAgIInsolubleLeast soluble silver halideCommon PrecipitateYellow precipitate, Ksp = 8.3 × 10⁻¹⁷
Lead(II) ChloridePbCl₂Slightly SolubleMore soluble in hot waterCommon PrecipitateWhite precipitate, Ksp = 1.7 × 10⁻⁵
Lead(II) IodidePbI₂InsolubleMore soluble in hot water (golden rain demo)Common PrecipitateBright yellow precipitate, Ksp = 7.9 × 10⁻⁹
Lead(II) SulfatePbSO₄InsolubleDissolves in concentrated H₂SO₄Common PrecipitateWhite precipitate, Ksp = 1.6 × 10⁻⁸
Barium SulfateBaSO₄InsolubleVery insoluble - used in medical imagingCommon PrecipitateWhite precipitate, Ksp = 1.1 × 10⁻¹⁰
Calcium CarbonateCaCO₃InsolubleDissolves in acid; more soluble in CO₂-rich waterCommon PrecipitateWhite precipitate (limestone, chalk), Ksp = 3.4 × 10⁻⁹
Calcium SulfateCaSO₄Slightly SolubleGypsum, plaster of ParisCommon PrecipitateWhite solid, Ksp = 2.4 × 10⁻⁵
Iron(III) HydroxideFe(OH)₃InsolubleDissolves in acidCommon PrecipitateRust-brown precipitate, Ksp = 6.3 × 10⁻³⁸
Copper(II) HydroxideCu(OH)₂InsolubleDissolves in NH₃ forming [Cu(NH₃)₄]²⁺ (deep blue)Common PrecipitateBlue precipitate, Ksp = 2.2 × 10⁻²⁰
Magnesium HydroxideMg(OH)₂Slightly SolubleMilk of Magnesia - antacidCommon PrecipitateWhite precipitate, Ksp = 1.8 × 10⁻¹¹
Aluminum HydroxideAl(OH)₃InsolubleAmphoteric - dissolves in both acid and baseCommon PrecipitateWhite gelatinous precipitate, Ksp = 3 × 10⁻³⁴
Zinc HydroxideZn(OH)₂InsolubleAmphoteric - dissolves in excess NaOHCommon PrecipitateWhite precipitate, Ksp = 3 × 10⁻¹⁷

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